Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2013 |
Shenzhen Gemdale Open
|
1/16 | Na Li |
7-5
6-3 |
| 2010 |
China Open
China, Beijing |
Championship | Vera Zvonareva |
3-6
3-6 |
| 2009 |
Sony Ericsson Open
United States, Florida, Miami |
Championship | Na Li |
6-4
3-6 6-2 |
| 2009 |
BNP Paribas Open
United States, California, Indian Wells |
Championship | Vera Zvonareva |
6-4
6-4 |
| 2008 |
Summer Olympics WTA
|
Championship | Vera Zvonareva |
6-0
7-5 |
| 2008 |
Qatar Ladies Open
|
Championship | Vera Zvonareva |
6-3
3-6 3-6 |
| 2007 |
BNP Paribas Open
|
Championship | Na Li |
4-6
5-7 |
| 2006 |
Qatar Ladies Open
|
Championship | Na Li |
4-6
4-6 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2020 |
Top Seed Open
|
1/16 | Jessica Pegula |
6-1
5-7 6-4 |
| 2020 |
Indian Wells
|
Semi Finals | Misaki Doi | |
| 2020 |
Indian Wells
|
Quarter Finals | Vera Zvonareva |
6-1
4-6 6-2 |
| 2020 |
Indian Wells
|
1/8 | Vera Zvonareva |
6-3
3-6 4-6 |
| 2020 |
Indian Wells
|
1/16 | Vera Zvonareva |
4-6
6-2 6-2 |
| 2020 |
Indian Wells
|
1/32 | Vera Zvonareva |
6-4
6-1 |
| 2020 |
Qatar Total Open
|
1/16 | Saisai Zheng |
5-7
1-6 |
| 2020 |
Qatar Total Open
|
1/32 | Vera Zvonareva |
4-6
4-6 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2014 |
Wimbledon WTA
|
1/16 | Barbora Strycova |
7-6
7-6 |
| 2014 |
Wimbledon WTA
|
1/32 | Na Li |
2-6
2-6 |
| 2014 |
Wimbledon WTA
|
1/64 | Na Li |
5-7
2-6 |
| 2014 |
Roland Garros WTA
|
1/64 | Kristina Mladenovic |
7-5
3-6 6-1 |
