Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2012 |
BGL BNP Paribas Luxembourg Open
|
1/16 | Jelena Jankovic |
3-0
|
| 2012 |
Western & Southern Financial Group Women
|
1/32 | Shuai Peng |
7-5
5-7 6-7 |
| 2011 |
Western & Southern Financial Group Women
|
Championship | Jelena Jankovic | |
| 2011 |
Australian Open WTA
Australia, Victoria, Melbourne |
Championship | Shuai Peng |
6-7
3-6 |
| 2009 |
China Open
China, Beijing |
Championship | Shuai Peng |
6-4
5-7 2-6 |
| 2008 |
Qatar Telecom German Open
Germany, Berlin |
Championship | Jelena Jankovic |
5-7
0-6 |
| 2007 |
East West Bank Classic presented by Herbalife
United States, California, Los Angeles |
Championship | Jelena Jankovic |
1-6
1-6 |
| 2007 |
Qatar Telecom German Open
|
Championship | Jelena Jankovic |
1-6
7-6 3-2 |
| 2007 |
Sony Ericsson Open
United States, Florida, Miami |
Championship | Jelena Jankovic |
6-2
6-4 |
| 2006 |
Landsky Lighting Guangzhou International Women's Open
|
Championship | Jelena Jankovic |
6-2
6-3 |
| 2006 |
AEGON Classic
|
Championship | Jelena Jankovic |
2-6
1-6 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2017 |
US Open WTA
|
1/64 | Petra Kvitova |
7-5
7-5 |
| 2017 |
Citi Open
|
1/16 | Oceane Dodin |
6-4
3-6 0-2 |
| 2017 |
NanChang Open
|
1/8 | Jing-Jing Lu |
2-6
6-1 6-2 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2020 |
Qatar Total Open, Qualification
|
1/16 | Magdalena Frech |
6-4
6-7 6-0 |
