Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2012 |
Brisbane International
Australia, Brisbane |
1/8 | Jelena Jankovic |
6-3
6-2 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2017 |
US Open WTA
|
1/64 | Petra Kvitova |
7-5
7-5 |
| 2017 |
Citi Open
|
1/16 | Oceane Dodin |
6-4
3-6 0-2 |
| 2017 |
NanChang Open
|
1/8 | Jing-Jing Lu |
2-6
6-1 6-2 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2013 |
US Open, Qualification WTA
|
1/32 | Chanel Simmonds |
6-0
6-2 |
| 2013 |
US Open, Qualification WTA
|
1/64 | Nina Bratchikova |
3-6
3-6 |
| 2013 |
Collector Swedish Open
Sweden, Bastad |
1/8 | Johanna Larsson |
6-2
6-3 |
| 2013 |
Collector Swedish Open
Sweden, Bastad |
1/16 | Nina Bratchikova |
3-6
1-6 |
