Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2017 |
US Open WTA
|
1/64 | Petra Kvitova |
7-5
7-5 |
| 2017 |
Citi Open
|
1/16 | Oceane Dodin |
6-4
3-6 0-2 |
| 2017 |
NanChang Open
|
1/8 | Jing-Jing Lu |
2-6
6-1 6-2 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2021 |
Open Sud de France
|
1/8 | Peter Gojowczyk |
7-6
6-7 3-6 |
| 2021 |
Open Sud de France
|
1/16 | Jiri Vesely |
1-6
1-6 |
| 2021 |
Australian Open ATP
|
1/32 | Pablo Carreno Busta |
3-6
6-7 6-2 4-6 |
| 2021 |
Australian Open ATP
|
1/64 | Jiri Vesely |
4-6
6-3 7-6 3-6 3-6 |
| 2021 |
Murray River Open
|
Quarter Finals | Felix Auger-Aliassime |
6-7
0-0 |
| 2021 |
Murray River Open
|
1/8 | Jiri Vesely |
6-4
6-2 |
| 2021 |
Murray River Open
|
1/16 | Jiri Vesely |
7-5
6-7 3-6 |
| 2021 |
Murray River Open
|
1/32 | Jiri Vesely |
4-6
4-6 |
