Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2014 |
Australian Open WTA
Australia, Victoria, Melbourne |
1/32 | Maria Sharapova |
3-6
6-4 8-10 |
| 2008 |
Roland Garros WTA
France, Paris |
Championship | Maria Sharapova |
7-6
6-0 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2020 |
Australian Open WTA
|
1/64 | Donna Vekic |
6-3
6-4 |
| 2020 |
Brisbane International
|
1/16 | Jennifer Brady |
6-3
1-6 6-7 |
| 2019 |
US Open WTA
|
1/64 | Serena Williams |
6-1
6-1 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2017 |
Australian Open WTA
|
1/64 | Su-Wei Hsieh |
3-6
0-2 |
| 2016 |
US Open WTA
United States, New York, Flushing Meadows |
1/64 | Johanna Larsson |
4-6
2-6 |
| 2016 |
Cincinnati Masters, Qualification
|
1/12 (Special Qual) | Kurumi Nara |
6-1
7-5 |
| 2016 |
Cincinnati Masters, Qualification
|
1/24 (Special Qual) | Karin Knapp |
7-6
3-6 6-4 |
