Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2021 |
Nur-Sultan 2
|
1/8 | Taro Daniel |
6-2
6-4 |
| 2021 |
Nur-Sultan
|
1/8 | Mackenzie McDonald |
6-2
6-3 |
| 2021 |
Cherbourg
|
1/8 | Ruben Bemelmans |
6-4
7-6 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2017 |
US Open WTA
|
1/64 | Petra Kvitova |
7-5
7-5 |
| 2017 |
Citi Open
|
1/16 | Oceane Dodin |
6-4
3-6 0-2 |
| 2017 |
NanChang Open
|
1/8 | Jing-Jing Lu |
2-6
6-1 6-2 |
