Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2013 |
US Open, Qualification WTA
|
1/32 | Chanel Simmonds |
6-0
6-2 |
| 2013 |
US Open, Qualification WTA
|
1/64 | Nina Bratchikova |
3-6
3-6 |
| 2013 |
Collector Swedish Open
Sweden, Bastad |
1/8 | Johanna Larsson |
6-2
6-3 |
| 2013 |
Collector Swedish Open
Sweden, Bastad |
1/16 | Nina Bratchikova |
3-6
1-6 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2020 |
Australian Open WTA
|
1/64 | Donna Vekic |
6-3
6-4 |
| 2020 |
Brisbane International
|
1/16 | Jennifer Brady |
6-3
1-6 6-7 |
| 2019 |
US Open WTA
|
1/64 | Serena Williams |
6-1
6-1 |
