Kvitova and Muguruza were playing in Charleston for the first time since 2018 and 2013.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2018 |
Western & Southern Open
|
1/16 | Petra Kvitova |
6-3
2-6 6-3 |
| 2015 |
Mutua Madrid Open
|
Semi Finals | Petra Kvitova |
2-6
3-6 |
| 2014 |
Mutua Madrid Open
|
Quarter Finals | Petra Kvitova | |
| 2013 |
TEB BNP Paribas WTA Championships Red group
|
Championship | Serena Williams |
6-2
6-3 |
| 2013 |
Qatar Total Open
Qatar, Doha |
Quarter Finals | Serena Williams |
6-3
3-6 5-7 |
| 2012 |
Wimbledon WTA
|
Quarter Finals | Serena Williams |
6-3
7-5 |
| 2010 |
Wimbledon WTA
England, Wimbledon |
Championship | Serena Williams |
7-6
6-2 |
| 2010 |
Australian Open WTA
Australia, Victoria, Melbourne |
Championship | Serena Williams |
6-2
6-1 |
| 2008 |
East West Bank Classic presented by Herbalife
United States, California, Los Angeles |
Championship |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2021 |
Volvo Car Open
|
1/8 | Danka Kovinic |
6-4
6-1 |
| 2021 |
Volvo Car Open
|
1/16 | Petra Kvitova |
6-7
2-6 |
| 2021 |
Miami Open
|
1/8 | Elina Svitolina |
6-2
5-7 5-7 |
| 2021 |
Miami Open
|
1/16 | Petra Kvitova |
6-1
6-2 |
| 2021 |
Miami Open
|
1/32 | Petra Kvitova |
6-0
6-4 |
| 2021 |
Dubai Duty Free Tennis Championships
|
1/16 | Jil Teichmann |
2-6
4-3 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2021 |
Australian Open WTA
|
Semi Finals | Naomi Osaka |
6-3
6-4 |
| 2021 |
Australian Open WTA
|
Quarter Finals | Serena Williams |
6-3
6-3 |
| 2021 |
Australian Open WTA
|
1/8 | Serena Williams |
4-6
6-2 4-6 |
| 2021 |
Australian Open WTA
|
1/16 | Serena Williams |
6-7
2-6 |
| 2021 |
Australian Open WTA
|
1/32 | Serena Williams |
3-6
0-6 |
| 2021 |
Australian Open WTA
|
1/64 | Serena Williams |
1-6
1-6 |
| 2021 |
Yarra Valley Classic
|
Semi Finals | Ashleigh Barty | |
| 2021 |
Yarra Valley Classic
|
Quarter Finals | Serena Williams |
2-6
6-4 6-10 |
| 2021 |
Yarra Valley Classic
|
1/8 | Serena Williams |
1-6
4-6 |
| 2021 |
Yarra Valley Classic
|
1/16 | Serena Williams |
1-6
4-6 |
| 2020 |
Roland Garros WTA
|
1/32 | Tsvetana Pironkova | |
| 2020 |
Roland Garros WTA
|
1/64 | Serena Williams |
6-7
0-6 |
