Williams became the first in history to own a career Golden Slam in singles and doubles.
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2015 |
Internationaux de Strasbourg
|
1/8 | Jelena Jankovic |
3-6
3-6 |
| 2015 |
Qatar Total Open
|
1/16 | Jelena Jankovic |
0-6
2-6 |
| 2014 |
Tianjin Open 2014
|
1/8 | Saisai Zheng |
3-6
3-6 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2020 |
Fed Cup Group 1 - Asia/Oceania
|
Championship | Saisai Zheng |
6-1
6-0 |
| 2020 |
Qatar Total Open
|
Quarter Finals | Aryna Sabalenka |
6-3
6-7 3-6 |
| 2020 |
Qatar Total Open
|
1/8 | Saisai Zheng |
6-3
3-6 4-6 |
| 2020 |
Qatar Total Open
|
1/16 | Saisai Zheng |
5-7
1-6 |
| 2020 |
Qatar Total Open
|
1/32 | Saisai Zheng |
1-6
6-3 6-2 |
| year | Event | RND | Winner | Results |
|---|---|---|---|---|
| 2017 |
US Open WTA
|
1/64 | Petra Kvitova |
7-5
7-5 |
| 2017 |
Citi Open
|
1/16 | Oceane Dodin |
6-4
3-6 0-2 |
| 2017 |
NanChang Open
|
1/8 | Jing-Jing Lu |
2-6
6-1 6-2 |
